Professional Supply Pgh-10 Palladium Based Catalyst with Good Service

• Customization: Available
• CAS No.: No
• Formula: No
• Model NO.: PGH-10
• EINECS: No
• Status: Solid Catalyst
• Response Type: Polymerization
• Classification: Homogeneous Catalysts
• Usage: Positive Catalyst
• Effect Size: Promoter Catalysts
• Manufacturing Method: Mechanical Mixing
• Application Industry: Industry
• Type: Synthesis Material Intermediates
• Quality: Refined
• Appearance: Extrudate
• Colour: Light Brown
• Solubility: Soluble
• Transport Package: According to Customer′s Request
• Specification: 99%
• Trademark: No brand
• Origin: China
• HS Code: 69091100
• Production Capacity: 500mts/Year

Product Description

Professional supply PGH-10 palladium based catalyst with good service

 

palladium based catalyst PGH-10 for first-stage hydrogenation of pyroysis gas oil

PGH-10 serials catalysts for first-stage hydrogenation of pyroysis gas oil, composed of noble metal palladium as active component and aluminum oxide as support with adding of various additives, were mainly used in the selective hydrogenation of pyroysis gas oilC₆~C₇, C₆~C₈, C₅~C₉, which were the cracking byproducts in the process of ethylene production.

In order to meet the market demand, PGH-10A, a new brand catalyst for the first-stage hydrogenation of pyroysis gas oil at the beginning of this century. PGH-10A made greater improvement in water resistant, anti-arsenic, sulfur-tolerant and hydrogenation stability, etc. It was industrial applied successfully in the petrol devices of Yanshan Petrochemical, Shanghai Petrochemical, Lanzhou Petrochemical.

2. physical and chemical properties

Schedule 1  Comparison of PGH-10 and PGH-10A

Item	PGH-10	PGH-10A
Shape	light brown trefoil extrudates	light brown trefoil extrudates
Size(mm)	F2.8~3.0´3~15	F2.8~3.0´3~15
Bulk density (g/ml)	0.60±0.05	0.65±0.05
Specific surface area (m^2/g)	90±20	100±20
Water absorption (%)	≥70	≥60
Crushing strength (N/cm)	³40	³60
active component Pd(%)	≥0.27	≥0.30
Additive1(%)	0.8	1.1
Additive2(%)	0.8	1.2

The combination of support,active component and additive in  PGH-10A was more favorable to pyrolysis  hydrogenation.PGH-10A has not only high chemical stability, high thermal stability and low rate of carbon formation, but also good hydrogenation,anti-water, anti-impurities, anti-high-load performance.

3. Catalyst Use Claims

3.1 Catalyst Process Operating Conditions

operating pressure(MPa)	≥2.4
inlet temperature (ºC)	inital 30~50,end 90~110
hydrogen-oil ratio (fresh feed) (V)	60~120
space velocity  (fresh oil) (h^-1)	≤3.5

3.2 Composition of Hydrogenation Raw Oil

3.2.1 Disposal Oil

distillate	C6~ C8,C5~C9
boiling range (ºC)	50~175
diene content (gI2/100g.oil)	≤35
	≤70
	≤20
gum content (mg/100ml)	≤10
inorganic sulfur content (ppm)	≤3
water content(ppm)	≤400

3.2.2 Hydrogen

purity(v%)	≥85
CO+CO2(ppm)	≤5

3.2..3 Hydrogenation Product Index and Catalyst Lifetime

hydrogenation Product diene(gI2/100g.oil)	≤2.5
catalyst guarantee lifetime	24months
first run cycle	≥12months

4.  Comparative Evaluation of PGH-10A with competitive Catalyst

1000 h Comparative evaluation test of PGH-10A and competitive catalyst were carried in 100ml Insulation installation. The details were showed in following:

4.1 Evaluation Device

catalyst bed temperature of the evaluation device which was imported from Xytel companies USA was controlled in three sessions. The temperature difference of insulation  bed reactor was  < ±0.5 ºC between inside and outside. Raw materials oil, hydrogen were injected into the pre-heater and mixted. when the temperature of the mixture reached the target temperature,operating parameters were tracking controlled automatically by a computer. The reaction products were isolated after condensation: oil was injected into the product tank, exhaust gas was emptied after measurement and  diene value of oil were analysized.

4.2 Conditions of technological Evaluation

Operating pressure	2.8MPa
Inlet temperature	35~65ºC
Liquid hourly space velocity	3.5h^-1
Hydrogen-oil ratio	80:1(Vol)

4.3 Evaluation Materials

Raw materials oil was the whole distillate oil C₅~C₉ pyrolysis gas oil and its properties were showed in Table 3.

Schedule 3  properties of Raw materials oil

Distillation Range(ºC)
The beginning of boiling	10%	20%	30%	40%	50%	60%	70%	80%	90%	The end of boiling
39	58	66	73	79	86	93	104	121	151	172
Diene value 42.53gI2/100g

 

4.4 Evaluation results

1000 h Comparative evaluation test of PGH-10A and competitive catalyst were carried in 100ml Insulation installation. The result was showed in following:

Figure 1 Comparative evaluation  results of the hydrogenation product diene value with time on stream catalyzed by  PGH-10A and competitive catalyst

1000 hours operation process(the diene value of raw materials was up to 42.53gI/100g indicated PGH-10A was adapted to low-grade oil and good  hydrogenation performance and its catalytic activity was considerable to competitive catalyst in Figure 1. PGH-10A has a good hydrogenation performance and stability.

 

 

 

 

  

 

 

 

 

 

 

 

   

 

 

 

 

  

 

 

 

iii.Package:

The drums are lined with plastic bags or packed according to customers' requirements.

 

 

 

 

 

1.Professional synthesis laboratory and production base.

 

2.Strong synthesis team and service team.

 

3.Professional data management system.

 

4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/GC,MS,COA,SDS

 

5.(2000+Suppliers) Partners.Any inquiries will be replied within 24 hours.

 

6.Rich shipping methods,ex. Fedex,DHL,TNT,BY SEA and BY AIR.

 

7.Shipping information includes Commerical Invoice,Packing List,COA,Invoice,BSE/TSE.If your markets have any special requirements, please let us know.

 

8.We can accept various payment methods,L/C,T/T,Western Union etc.

 

9.Professional packaging can be according the customers'requirment.

 

10.Product application:  Medicinal Chemistry , Biomedicine, Pharmaceutical intermediate, Chemistry experiment ,Biological experiments ,Chemical reagent, For R&D use only.